Diisobutylaluminum hydride solution
ALDRICH/214973 - 1.0 M in methylene chloride
Synonym: DIBAL; DIBAL-H
CAS Number: 1191-15-7
Empirical Formula (Hill Notation): C8H19Al
Molecular Weight: 142.22
MDL Number: MFCD00008928
Linear Formula: [(CH3)2CHCH2]2AlH
Product Type: Chemical
concentration | 1.0 M in methylene chloride |
density | 1.23 g/mL at 25 °C |
form | liquid |
InChI | 1S/2C4H9.Al.H/c2*1-4(2)3; |
InChI key | AZWXAPCAJCYGIA-UHFFFAOYSA |
Quality Level | 200 |
reaction suitability | reagent type: reductant |
SMILES string | CC(C)C[AlH]CC(C)C |
storage temp. | 2-8°C |
Application: | Diisobutylaluminum hydride solution (1 M in dichloromethane) has been used in the conversion of esters into α-fluoro-α,β-unsaturated esters in the presence of fluorocarboalkoxy-substit |
Application: | Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H. |
General description: | Diisobutylaluminum hydride is a reducing agent for many functional groups commonly used in organic synthesis. |
Packaging: | 1 L in Sure/Seal™ |
Packaging: | 100, 800 mL in Sure/Seal™ |
Symbol | GHS02,GHS05,GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H250 - H260 - H314 - H336 - H351 |
Precautionary statements | P201 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
Hazard Codes | F,C |
Risk Statements | 11-14/15-34-37-40-67 |
Safety Statements | 16-26-36/37/39-43-45 |
RIDADR | UN 3394 4.3(4.2) / PGI |
WGK Germany | WGK 2 |
Supplemental Hazard Statements | EUH014 |
Density | 1.23 g/mL at 25 °C |
Storage Temp. | 2-8°C |
UNSPSC | 12352001 |