Manganese(III) acetate dihydrate
ALDRICH/215880 - 97%
Synonym: Manganese triacetate dihydrate
CAS Number: 19513-05-4
Empirical Formula (Hill Notation): C6H9MnO6 · 2H2O
Molecular Weight: 268.10
EC Number: 213-602-5
MDL Number: MFCD00150022
Linear Formula: (CH3COO)3Mn · 2H2O
Product Type: Chemical
| assay | 97% |
| form | powder or chunks |
| InChI | 1S/3C2H4O2.Mn.2H2O/c3*1-2 |
| InChI key | ONJSLAKTVIZUQS-UHFFFAOYSA |
| Quality Level | 100 ![]() |
| reaction suitability | core: manganese |
| SMILES string | O.O.CC(=O)O[Mn](OC(C)=O)O |
| Application: | Manganese(III) acetate dihydrate can be used as: • A precursor in the synthesis of manganese oxide (Mn3O4) nanostructures, which are employed as anode materials in lithium-ion batteries. • A manganese source in the sol-gel synthesis of Mn-doped ZnO thin films. The incorporation of manganese ions into the ZnO lattice is essential for modifying the electronic and optical properties of the films. • A precursor for the synthesis of manganese oxide nanoparticles using a sol-gel process. These nanoparticles are evaluated for their performance in supercapacitor applications. • A mild and selective oxidizing agent. Catalyzes allylic oxidation of a variety of alkenes in the presence of tert-butylhydroperoxide. Reagent used for radical cyclizations and α-keto-acetoxylation. |
| General description: | Manganese(III) acetate dihydrate is a coordination compound of manganese in the +3 oxidation state, exhibiting moderate solubility in water and acetic acid. It is used as a precursor for synthesizing manganese oxides and other manganese-containing materials. These materials have applications in batteries, catalysis, and other energy-related technologies. Additionally, it is also used as a mild and selective oxidizing agent in organic synthesis. |
| Packaging: | 25, 100 g in poly bottle |
| Packaging: | 5 g in glass bottle |
| Physical form: | Crystallographic evidence suggests this material is an oxo-centered triangle of Mn(III) with bridging acetates having the molecular formula: Mn3O(OAc)9 · 6H2O. |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Purity | 97% |
| UNSPSC | 12352103 |

