Cesium hydrogencarbonate
ALDRICH/218227 - 99.9%
Synonym: Cesium bicarbonate
CAS Number: 29703-01-3
Empirical Formula (Hill Notation): CHCsO3
Molecular Weight: 193.92
EC Number: 249-784-8
MDL Number: MFCD00010961
Linear Formula: CsHCO3
Product Type: Chemical
assay | 99.9% |
form | solid |
InChI | 1S/CH2O3.Cs/c2-1(3)4;/h(H |
InChI key | ZMCUDHNSHCRDBT-UHFFFAOYSA |
Quality Level | 100 |
SMILES string | [Cs+].OC([O-])=O |
Application: | Cesium hydrogencarbonate can be used as a base:• In the Ni-catalyzed hydroarylation of unactivated alkenes with arylboronic acids to synthesize arylated alkanes. • To synthesize 5-phenylthiazolamines by coupling thiourea with phenylacetones, phenylacetophenones, and β-tetralone in the presence of CBrCl3. • In the Pd-catalyzed hydroxycarbonylation of aryl halides. • In the regioselective alkylation of 2,4-dihydroxybenzyaldehyd It can also be used as a catalyst for the:• Etherification of glycerol to oligomers. • Acetylation of primary alcohols and phenols to acetates using acetic anhydride. |
General description: | Cesium hydrogencarbonate is used as a source of bicarbonate ions. |
Packaging: | 25, 100 g in glass bottle |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 99.9% |
UNSPSC | 12352302 |