K-Selectride^® solution

ALDRICH/220760 - 1.0 M potassium tri-sec-butylborohydride in THF

Synonym: Potassium tri-sec-butylborohydride solution

CAS Number: 54575-49-4
Empirical Formula (Hill Notation): C₁₂H₂₈BK
Molecular Weight: 222.26
MDL Number: MFCD00009324
Linear Formula: K[CH(CH₃)CH₂CH₃]₃BH
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-220760-100ML	100 mL	$207.00 1/EA	Add To Favorites
45-220760-800ML	800 mL	$886.00 1/EA	Add To Favorites

25 mL Sure/Seal™ Packaging

Properties
Descriptions
Safety Info.
Basic Data

concentration	1.0 M potassium tri-sec-butylborohydride in THF
density	0.913 g/mL at 25 °C
form	liquid
InChI	1S/C12H28B.K/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
InChI key	NHEDTYWJTOUTDG-UHFFFAOYSA-N
Quality Level	200
reaction suitability	reagent type: reductant
SMILES string	[H][B]([K])(C(C)CC)(C(C)CC)C(C)CC

Application:	• Reducing reagent Reactant for: • Preparation of a PCP-pincer palladium hydride-K-Selectride complex • Formation of P-H, P-C, and C-H bonds by hydride attack • Stereoselective conjugate hydride reduction reactions
Application:	Stereoselective reducing agent for ketones. Hydride employed in regioselective reactions with transition metal ligands.
Legal Information:	Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany
Packaging:	100, 800 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H260 - H314 - H335 - H336 - H351
Precautionary statements	P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-14/15-19-34-37-40
Safety Statements	16-26-36/37/39-43-45
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 3
Flash Point(F)	1.4 °F
Flash Point(C)	-17 °C
Supplemental Hazard Statements	EUH019

Density	0.913 g/mL at 25 °C
UNSPSC	12352001

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