Allylpalladium(II) chloride dimer
ALDRICH/222380 - 98%
Synonym: Bis((η3-allyl)(chloro)palladium), Di-ο-allyldi-μ-chlorodipalladium; [PdCl(C3H5)]2
CAS Number: 12012-95-2
Empirical Formula (Hill Notation): C6H10Cl2Pd2
Molecular Weight: 365.89
EC Number: 234-579-8
MDL Number: MFCD00044874
Linear Formula: C6H10Cl2Pd2
Product Type: Chemical
[PdCl(C3H5)]2
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 222380-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 222380-5G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 222380-500MG
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.
| assay | 98% |
| form | solid |
| greener alternative category |  , Aligned |
| greener alternative product characteristics | Catalysis Learn more about the Principles of Green Chemistry . |
| InChI | 1S/2C3H5.2ClH.2Pd/c2*1-3- |
| InChI key | TWKVUTXHANJYGH-UHFFFAOYSA |
| Quality Level | 200 |
| reaction suitability | core: palladium |
| reaction type: Cross Couplings | |
| reagent type: catalyst reaction type: C-H Activation |
|
| SMILES string | Cl[Pd]CC=C.Cl[Pd]CC=C |
| storage temp. | 2-8°C |
| sustainability | Greener Alternative Product |
| Application: | Application Guide for Palladium Catalyzed Cross-Coupling Reactions |
| Application: | Allylpalladium(II) chloride dimer has been employed for the following studies: • Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation. • Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides. • Synthesis of 1,4-diallyl-1,2-dihydrois • As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M. On the Way Towards Greener Transition-Metal-Catalyze  |
| General description: | Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylati |
| General description: | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. |
| Packaging: | 1, 5 g in glass bottle |
| Packaging: | 5 mg in ampule |
| Packaging: | 500 mg in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 |
| Precautionary statements | P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Purity | 98% |
| Storage Temp. | 2-8°C |
| UNSPSC | 12161600 |