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Tris(triphenylphosphine)ruthenium(II) dichloride

ALDRICH/223662 - 97%

Synonym: Tris(triphenylphosphine)dichlororuthenium; Dichlorotris(triphenylphosphine)ruthenium(II); Ruthenium(II)-tris(triphenylphosphine) dichloride

CAS Number: 15529-49-4
Empirical Formula (Hill Notation): C54H45Cl2P3Ru
Molecular Weight: 958.83
EC Number: 239-569-7
MDL Number: MFCD00013077
Linear Formula: [(C6H5)3P]3RuCl2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-223662-1G 1 g
 $70.30
1/EA		 Add To Favorites
45-223662-5G 5 g
 $172.00
1/EA		 Add To Favorites
45-223662-25G 25 g
 $471.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 223662-25G

 

assay 97%
InChI 1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChI key WIWBLJMBLGWSIN-UHFFFAOYSA-L
Quality Level 100 
reaction suitability core: ruthenium
  reagent type: catalyst
reaction type: C-H Activation
SMILES string Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
Application: Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl2(PPh3)3] can be used as a catalyst to synthesize:
• Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp3 C-H bond activation of primary alcohols in the presence of Lewis acid.
• Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.
• 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.
• Vinyl chloride monomer by hydrochlorination reaction of acetylene.

RuCl2(PPh3)3 can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.
Packaging: 1, 5, 25 g in glass bottle
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 36/37
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
UNSPSC 12352300

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