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Bis(benzonitrile)palladium(II) chloride

ALDRICH/223689 - 95%

Synonym: Benzonitrile, palladium complex; Bis(benzonitrile)dichloropalladium(II); Bis(benzonitrile)palladium(II) chloride; Bis(phenylnitrile)dichloropalladium; Dibenzonitrilepalladium dichloride; Dichlorobis(benzonitrile)palladium; Dichlorobis(benzonitrile)palladium(II); Dichlorobis(phenyl cyanide)palladium; Palladium dichloride bis(benzonitrile); Palladium(II) chloride bis(benzonitrile) complex

CAS Number: 14220-64-5
Empirical Formula (Hill Notation): C14H10Cl2N2Pd
Molecular Weight: 383.57
EC Number: 238-085-3
MDL Number: MFCD00013123
Linear Formula: (C6H5CN)2PdCl2
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-223689-1G 1 g
$87.60
1/EA
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45-223689-10G 10 g
$806.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 223689-1G
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

 

assay 95%
form powder
greener alternative category Aligned ,  
greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry .
InChI 1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI key WXNOJTUTEXAZLD-UHFFFAOYSA-L
mp 131 °C (lit.)
Quality Level 100 
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
SMILES string Cl[Pd]Cl.N#Cc1ccccc1.N#Cc2ccccc2
sustainability Greener Alternative Product
Application: Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:
• For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
• In cross-coupling reactions and α-O-glycosidation.

Formal anti-Markovnikov hydroamination of terminal olefins 
General description: Bis(benzonitrile)palladium(II) chloride is a coordination compound used as a catalyst in the Suzuki Cross-Coupling reaction.


We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here .
Packaging: 1, 10 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 95%
mp 131 °C (lit.)
UNSPSC 12352300

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