Phenylmagnesium chloride solution

ALDRICH/224448 - 2.0 M in THF

Synonym: Chlorophenylmagnesium

CAS Number: 100-59-4
Empirical Formula (Hill Notation): C₆H₅ClMg
Molecular Weight: 136.86
MDL Number: MFCD00000464
Linear Formula: C₆H₅MgCl
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-224448-100ML	100 mL	$84.90 1/EA		Add To Favorites
45-224448-800ML	800 mL	$279.00 1/EA		Add To Favorites
45-224448-8L	8 L	$2460.00 1/EA		Add To Favorites
45-224448-18L-KL	18 L	$4730.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	2.0 M in THF
density	1.042 g/mL at 25 °C
	~1.02 g/mL at 20 °C
InChI	1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChI key	GQONLASZRVFGHI-UHFFFAOYSA-M
Quality Level	200
reaction suitability	reaction type: Grignard Reaction
SMILES string	Cl[Mg]c1ccccc1

Application:	Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (−)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl₃) in the rechargeable magnesium batteries.
Other Notes:	Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid
Packaging:	100, 800 mL in Sure/Seal™
Packaging:	8, 18 L in Kilo-Lab™
Packaging:	View returnable container options .

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H314 - H335 - H336 - H351
Precautionary statements	P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-14-19-34-37-40
Safety Statements	16-26-36/37/39-45
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17 °C - closed cup
Supplemental Hazard Statements	EUH019

Density	~1.02 g/mL at 20 °C; 1.042 g/mL at 25 °C
UNSPSC	12352103

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