tert-Butylmagnesium chloride solution

ALDRICH/224499 - 2.0 M in diethyl ether

Synonym: t-Butylmagnesium chloride; tert-Butylchloromagnesium; Chloro(1,1-dimethylethyl)magnesium

CAS Number: 677-22-5
Empirical Formula (Hill Notation): C₄H₉ClMg
Molecular Weight: 116.87
MDL Number: MFCD00000465
Linear Formula: (CH₃)₃CMgCl
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-224499-100ML	100 mL	$75.90 1/EA	Add To Favorites
45-224499-800ML	800 mL	$364.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	2.0 M in diethyl ether
density	0.828 g/mL at 25 °C
InChI	1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
InChI key	ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Quality Level	200
reaction suitability	reaction type: Grignard Reaction
SMILES string	CC(C)(C)[Mg]Cl

Application:	tert-Butylmagnesium chloride solution can be used as a Grignard reagent:• In the Fe-catalyzed cross-coupling reaction with chloroenynols. • To synthesize alkyne-terminated polyhexylthiophenes.
Packaging:	100, 800 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07
Signal word	Danger
Hazard statements	H225 - H250 - H260 - H302 - H314 - H336
Precautionary statements	P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
Hazard Codes	F,C
Risk Statements	11-14-17-19-22-34-67
Safety Statements	16-26-36/37/39-45
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 3
Flash Point(F)	-40.0 °F - closed cup
Flash Point(C)	-40 °C - closed cup
Supplemental Hazard Statements	EUH019

Density	0.828 g/mL at 25 °C
UNSPSC	12352103

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