Bismuth(III) chloride
ALDRICH/224839 - reagent grade, ≥98%
Synonym: Bismuth trichloride; Trichlorobismuth
CAS Number: 7787-60-2
Empirical Formula (Hill Notation): BiCl3
Molecular Weight: 315.34
EC Number: 232-123-2
MDL Number: MFCD00003461
Linear Formula: BiCl3
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.
This image depicts SKU: 224839-500G
This image depicts SKU: 224839-500G
| assay | ≥98% |
| bp | 447 °C (lit.) |
| form | powder, chunks or granules |
| grade | reagent grade |
| InChI | 1S/Bi.3ClH/h;3*1H/q+3;;;/ |
| InChI key | JHXKRIRFYBPWGE-UHFFFAOYSA |
| mp | 230-232 °C (lit.) |
| Quality Level | 100  |
| reaction suitability | reagent type: catalyst core: bismuth |
| SMILES string | Cl[Bi](Cl)Cl |
| Application: | Bismuth(III) chloride may be used as a catalyst in the following processes: • Alcoholysis, acetolysis and hydrolysis of epoxides to form the corresponding β-alkoxy and β-acetoxy alcohols and diols. • Preparation of thiiranes from oxiranes using ammonium thiocyanate. • Three component coupling of carbonyl compound, amine and dialkyl phosphite to form α-amino phosphonates. • Allylation of secondary benzyl alcohols with allyltrimethylsilane. • [4 + 2] cycloaddition between dienes and α-carbonyl ethylenic dienophiles. |
| General description: | Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine. |
| Packaging: | 25, 100, 500 g in poly bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 |
| Precautionary statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/38 |
| Safety Statements | 26-36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 2 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥98% |
| bp | 447 °C (lit.) |
| mp | 230-232 °C (lit.) |
| UNSPSC | 12352300 |