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Tris(triphenylphosphine)rhodium(I) carbonyl hydride

ALDRICH/225665 - 97%

Synonym: RhH(CO)(PPh3)3; Rhodium monocarbonyl hydrogen tris(triphenylphosphine); Tris(triphenylphosphine)carbonylrhodium hydride; trans-Carbonyl(hydrido)tris(triphenylphosphine)rhodium; Carbonyltris(triphenylphosphine)rhodium(I) hydride; Hydridocarbonyl-tris(triphenylphosphine)-rhodium(I); Rhodium(I) tris(triphenylphosphine) carbonyl hydride

CAS Number: 17185-29-4
Empirical Formula (Hill Notation): C55H46OP3Rh
Molecular Weight: 918.78
EC Number: 241-230-3
MDL Number: MFCD00151644
Linear Formula: [(C6H5)3P]3Rh(CO)H
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-225665-500MG 500 mg
 $251.00
1/EA		 Add To Favorites
45-225665-5G 5 g
 $1760.00
1/EA		 Add To Favorites

 

assay 97%
form solid
InChI 1S/3C18H15P.CO.Rh.H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;;
InChI key AACIZACVKFEETJ-UHFFFAOYSA-N
mp 150 °C (dec.) (lit.)
Quality Level 100 
reaction suitability core: rhodium
  reagent type: catalyst
SMILES string [RhH].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
Application: Catalyzes the ring-opening isomeriztion of methylenecyclopropanes to 1,3-dienes.
Features and Benefits: Homogeneous catalyst.
Packaging: 5 g in glass bottle
Packaging: 500 mg in amber glass bottle
Hazard Codes T
Risk Statements 23/24/25
Safety Statements 36/37-45
RIDADR NONH for all modes of transport
WGK Germany WGK 1
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
mp 150 °C (dec.) (lit.)
UNSPSC 12352300

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