Allylmagnesium bromide solution

ALDRICH/225754 - 1.0 M in diethyl ether

Synonym: (Prop-2-en-1-yl)magnesium bromide; 2-Propenylmagnesium bromide; Allyl magnesium bromide; Allylbromomagnesium; Allylmagnesiumbromide; Bromo-2-propenylmagnesium

CAS Number: 1730-25-2
Empirical Formula (Hill Notation): C₃H₅BrMg
Molecular Weight: 145.28
MDL Number: MFCD00000044
Linear Formula: CH₂=CHCH₂MgBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-225754-100ML	100 mL	$68.90 1/EA	Add To Favorites
45-225754-800ML	800 mL	$375.00 1/EA	Add To Favorites
45-225754-18L	18 L	$3570.00 1/EA	Add To Favorites

25 mL Sure/Seal™ Packaging

Properties
Descriptions
Safety Info.
Basic Data

concentration	1.0 M in diethyl ether
density	0.851 g/mL at 25 °C
InChI	1S/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1
InChI key	FEMBXICCJNZMMC-UHFFFAOYSA-M
Quality Level	100
reaction suitability	reaction type: Grignard Reaction
SMILES string	Br[Mg]CC=C

Application:	Allylmagnesium bromide solution can be used in the Grignard reaction, which is a key step to synthesize: • 2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanamine (2), a homolog of benzoctamine • tarchonanthuslactone • (+)-preussin • polyhydroxylated quinolizidine alkaloids
General description:	Allylmagnesium bromide solution serves as a selective nucleophile toward aza-aromatic heterocycles.
Packaging:	100, 800 mL in Sure/Seal™
Packaging:	18 L in Kilo-Lab™
Packaging:	View returnable container options .

Symbol	GHS02,GHS05,GHS07
Signal word	Danger
Hazard statements	H225 - H250 - H260 - H302 - H314 - H336
Precautionary statements	P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
Hazard Codes	F,C
Risk Statements	11-14/15-19-22-34-67
Safety Statements	16-26-36/37/39-43-45
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 1
Flash Point(F)	-40.0 °F - closed cup
Flash Point(C)	-40 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

Density	0.851 g/mL at 25 °C
UNSPSC	12352103

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