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Allylmagnesium chloride solution

ALDRICH/225908 - 2.0 M in THF

Synonym: Allyl magnesium chloride; Allylchloromagnesium; Allylmagnesium chloride; Chloro-2-propen-1-ylmagnesium

CAS Number: 2622-05-1
Empirical Formula (Hill Notation): C3H5ClMg
Molecular Weight: 100.83
MDL Number: MFCD00000473
Linear Formula: CH2=CHCH2MgCl
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-225908-100ML 100 mL
 $82.10
1/EA		 Add To Favorites
45-225908-800ML 800 mL
 $447.00
1/EA		 Add To Favorites
45-225908-18L 18 L
 $6420.00
1/EA		 Add To Favorites

 

concentration 2.0 M in THF
density 0.995 g/mL at 25 °C
InChI 1S/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1
InChI key PLYLAFITHJUEGX-UHFFFAOYSA-M
Quality Level 100 
reaction suitability reaction type: Grignard Reaction
SMILES string Cl[Mg]CC=C
Application: Allylmagnesium chloride solution is used as a Grignard reagent in the preparation of:
• Antipsychotic clopixol.
• Polysilane–crown ether polymer (PSEC) using hexachloroplatinic acid as a catalyst.
• 1,7-disubstituted-1,2,3,4-tetrahydroisoquinolinesfrom 3,4-dihydroisoquinoline.
General description: Allylmagnesiumchloride solution is an organic compound commonly used as a Grignard reagent inchemical reactions. It is used for the allylation of carbonyl compounds, such as aldehydes and ketones.
Packaging: 100, 800 mL in Sure/Seal™
Packaging: 18 L in Kilo-Lab™
Symbol GHS02GHS05GHS07GHS08  GHS02,GHS05,GHS07,GHS08
Signal word Danger
Hazard statements H225 - H260 - H314 - H335 - H336 - H351
Precautionary statements P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes F,C
Risk Statements 11-14/15-19-34-37-40
Safety Statements 16-26-36/37/39-43-45
RIDADR UN 3399A 4.3(3) / PGI
WGK Germany WGK 1
Flash Point(F) 1.4 °F - closed cup - Solve
Flash Point(C) -17 °C - closed cup - Solve
Supplemental Hazard Statements EUH014 - EUH019
Density 0.995 g/mL at 25 °C
UNSPSC 12352103

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