Cobalt(II) acetylacetonate

ALDRICH/227129 - 97%

Synonym: 2,4-Pentanedione cobalt(II) derivative; Bis(2,4-pentanedionato)cobalt; Co(acac)₂; Cobaltous acetylacetonate

CAS Number: 14024-48-7
Empirical Formula (Hill Notation): C₁₀H₁₄CoO₄
Molecular Weight: 257.15
EC Number: 237-855-6
MDL Number: MFCD00000014
Linear Formula: Co(C₅H₇O₂)₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-227129-50G	50 g	$169.00 1/EA	Add To Favorites
45-227129-250G	250 g	$389.00 1/EA	Add To Favorites

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This image depicts SKU: 227129-50G

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
form	powder and chunks
impurities	≤3% water
InChI	1S/2C5H8O2.Co/c21-4(6)3-5(2)7;/h23,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InChI key	UTYYEGLZLFAFDI-FDGPNNRMSA-L
mp	165-170 °C (lit.)
Quality Level	200
reaction suitability	core: cobalt
SMILES string	CC(=O)C=C(C)O[Co]OC(C)=C/C(C)=O

Application:	Cobalt (II)-Catalyzed Isocyanide Insertion Reaction with Amines: Details a synthetic method for forming ureas and azaheterocycles catalyzed by Cobalt(II) acetylacetonate, applicable in pharmaceutical synthesis (Zhu et al., 2014 ). Cobalt‐Catalyzed C−H Functionalizations by Imidate Assistance: Describes a method using Cobalt(II) acetylacetonate for C-H functionalization, important for organic synthesis and material chemistry (Mei & Ackermann, 2016 ). Cobalt (II) acetylacetonate covalently anchored onto magnetic mesoporous silica nanospheres: Focuses on its use as a catalyst for epoxidation of olefins, relevant for catalysis research (Li et al., 2015 ).
Application:	Cobalt(II) acetylacetonate can be used: • A precursor in the solvothermal synthesis of Co₃O₄ nanoparticles. These nanoparticles exhibit high electrochemical performance and are used as a potential supercapacitor material due to their excellent capacitance and cycling stability. • A precursor in the preparation of Co₃O₄ nanoparticles via hydrothermal method. The resulting Co₃O₄ nanoparticles exhibit a highly-uniform mesoporous structure and tunable sizes, making them promising for CO sensing applications. • A precursor for the growth of cobalt oxide thin films using Metal-Organic Chemical Vapor Deposition (MOCVD).
General description:	Cobalt(II)acetylacetonate (Co(acac)₂) is a coordination compound in which acentral cobalt atom is coordinated to two acetylacetonate ligands, which act asbidentate ligands. It is used in various applications such as organicsynthesis, coordination chemistry, and as a catalyst in several chemicalreactions. Additionally, Co(acac)₂ is used as a precursor in processes such aschemical vapor deposition (CVD) and laser evaporation techniques for thefabrication of thin films. It also plays a crucial role in the production ofcobalt oxide thin films, which find applications in electronics, catalysis, andother fields requiring thin film coatings.
Packaging:	250 g in glass bottle
Packaging:	50 g in poly bottle

Symbol	GHS05,GHS07,GHS08,GHS09
Signal word	Danger
Hazard statements	H302 - H317 - H318 - H360F - H410
Precautionary statements	P201 - P273 - P280 - P301 + P312 + P330 - P305 + P351 + P338 + P310 - P308 + P313
Hazard Codes	Xn
Risk Statements	20/21/22-41
Safety Statements	7-22-26-37/39
RIDADR	UN 3077 9 / PGIII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	97%
mp	165-170 °C (lit.)
UNSPSC	12352103

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