2-Mesitylmagnesium bromide solution
ALDRICH/227234 - 1.0 M in THF
Synonym: 2,4,6-
CAS Number: 2633-66-1
Empirical Formula (Hill Notation): C9H11BrMg
Molecular Weight: 223.39
MDL Number: MFCD00009663
Linear Formula: (CH3)3C6H2MgBr
Product Type: Chemical
concentration | 1.0 M in THF |
density | 1.005 g/mL at 25 °C |
InChI | 1S/C9H11.BrH.Mg/c1-7-4-8( |
InChI key | YXVSITSUDRGILL-UHFFFAOYSA |
Quality Level | 100 |
reaction suitability | reaction type: Grignard Reaction |
SMILES string | Cc1cc(C)c([Mg]Br)c(C)c1 |
Application: | 2-Mesitylmagnesium bromide is a Grignard reagent generally used to synthesize stable aromatic radical species such as dibenzoheptazethrene, diindenoanthracene, teranthene and dimesitylindeno[2,1-a]fluorene by kinetically blocking reactive molecular sites. It is also used in a variety of aromatic cross-coupling reactions. |
Packaging: | 100, 800 mL in Sure/Seal™ |
Symbol | GHS02,GHS05,GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H225 - H314 - H335 - H351 |
Precautionary statements | P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235 |
Hazard Codes | F,C |
Risk Statements | 11-14-19-34-37-40 |
Safety Statements | 16-26-36/37/39-45 |
RIDADR | UN 2924 8(3) / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | 1.4 °F - closed cup |
Flash Point(C) | -17.0 °C - closed cup |
Supplemental Hazard Statements | EUH014 - EUH019 |
Density | 1.005 g/mL at 25 °C |
UNSPSC | 12352103 |