Chloro(1,5-cyclooctadiene)rhodium(I) dimer

ALDRICH/227951 - 98%

Synonym: 1,5-Cyclooctadienerhodium(I) chloride dimer; Bis(1,5-cyclooctadiene)dirhodium(I) dichloride; Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium; Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer; [Rh(COD)Cl]₂

CAS Number: 12092-47-6
Empirical Formula (Hill Notation): C₁₆H₂₄Cl₂Rh₂
Molecular Weight: 493.08
EC Number: 235-157-6
MDL Number: MFCD00012415
Linear Formula: C₁₆H₂₄Cl₂Rh₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-227951-500MG	500 mg	$497.00 1/EA	Add To Favorites
45-227951-5G	5 g	$3830.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 227951-5G

12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
form	solid
greener alternative category	Aligned ,
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry .
InChI	1S/2C8H12.2ClH.2Rh/c21-2-4-6-8-7-5-3-1;;;;/h21-2,7-8H,3-6H2;21H;;/q;;;;2+1/p-2/b2*2-1-,8-7-;;;;
InChI key	QSUDXYGZLAJAQU-MIXQCLKLSA-L
mp	243 °C (dec.) (lit.)
Quality Level	100
reaction suitability	core: rhodium
	reagent type: catalyst
SMILES string	Cl[Rh].Cl[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
sustainability	Greener Alternative Product

Application:	Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis Efficient and Selective Catalysts for Asymmetric Synthesis
Application:	Catalyst for coupling 1,3-dienes with activated hydrocarbons and for preparing chiral complexes.
Application:	Catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids. Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids
General description:	We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here .
Packaging:	5, 50 g in glass bottle
Packaging:	500 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H319
Precautionary statements	P264 - P280 - P305 + P351 + P338 - P337 + P313
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3

Purity	98%
mp	243 °C (dec.) (lit.)
UNSPSC	12352300

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