Advanced Search



Bis(dibenzylideneacetone)palladium(0)

ALDRICH/227994

Synonym: Palladium(0) bis(dibenzylideneacetone); Pd(dba)2

CAS Number: 32005-36-0
Empirical Formula (Hill Notation): C34H28O2Pd
Molecular Weight: 575.00
MDL Number: MFCD00051942
Linear Formula: (C6H5CH=CHCOCH=CHC6H5)2Pd
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-227994-500MG 500 mg
 $49.00
1/EA		 Add To Favorites
45-227994-2G 2 g
 $155.00
1/EA		 Add To Favorites
45-227994-5G 5 g
 $221.00
1/EA		 Add To Favorites
45-227994-50G 50 g
 $2030.00
1/EA		 Add To Favorites
Pd(dba)2
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 227994-50G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 227994-2G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 227994-5G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 227994-500MG

 

form powder
InChI 1S/2C17H14O.Pd/c2*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;/h2*1-14H;/b2*13-11+,14-12+;
InChI key UKSZBOKPHAQOMP-SVLSSHOZSA-N
Quality Level 100 
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Cross Couplings
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
SMILES string [Pd].O=C(/C=C/c1ccccc1)C=Cc2ccccc2.O=C(/C=C/c3ccccc3)C=Cc4ccccc4
Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions 
Application: Bis(dibenzylideneacetone)palladium(0) (Pd(dba)2) was employed as catalyst in the following studies:
• Synthesis of isomeric 2-aryl-2,5-dihydrofurans, via Heck coupling of aryl bromides with alkenes using neopentyl phosphine ligands.
• Heck reaction of benzyl trifluoroacetate and 2,3-dihydrofuran phosphoramidite ligand.
• Allylation of stabilized anions.
• Cross coupling of allyl, alkenyl and aryl halides with organostannanes.
• Cross coupling of vinyl halides with alkenyl zinc species.
• Carbonylation of alkenyl and aryl halides.
• Employed with cyclic thiourea ligands in an efficient aerobic oxidation of alcohols to aldehydes and ketones.
General description: Bis(dibenzylideneacetone)palladium(0) (Pd(dba)2) is an air stable Pd0 complex. It is a reagent for the synthesis of allylic substituted cyclopentadienes. It is a homogeneous catalyst. It catalyzes the alkylation of allyl acetates by various nucleophiles under mild conditions.
Packaging: 2, 5, 50 g in glass bottle
Packaging: 500 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
UNSPSC 12161600

The following items have been added to your cart:

Choose a favorite list for this item:
Catalog Number Description Price
$

Returns/Order support

Please fill out the form below if you want to request order support from Krackeler Scientific.


Quick Order

* Required


New Year Price Updates

We are currently working diligently to update our website pricing information for the New Year. If you place an order, you will be acknowledged with any corrected pricing. If you'd like the most current information sooner, please don't hesitate to drop us an email or give us a call and we'd be happy to assist. Thank you for your patience while we are updating.

800-334-7725
office@krackeler.com


Play Video

To Request a Quote

  1. Search or Browse for items and add to them to your Shopping Cart.
  2. Click the "Request Quote" button at the bottom of the Shopping Cart page.
  3. Fill out required fields.
  4. Optionally you can convert to standard checkout mode by choosing a payment type.
  5. Click "Request Quote" at the bottom of the page.

You will be contacted with a quote.

To Order From a Quote

  1. Register and login to the website.
  2. Receive a quote from your sales representative or customer service.
  3. Have your copy of the quote in hand.
  4. Visit our quote module to search for your quote.
Back to Top