(1-Chloroethyl)trimethylsilane

ALDRICH/23070 - technical, ≥90% (GC)

CAS Number: 7787-87-3
Empirical Formula (Hill Notation): C₅H₁₃ClSi
Molecular Weight: 136.70
EC Number: 232-135-8
MDL Number: MFCD00042611
Linear Formula: C₅H₁₃ClSi
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-23070-5ML	5 mL	$382.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	≥90% (GC)
bp	116 °C (lit.)
density	0.864 g/mL at 20 °C (lit.)
form	liquid
grade	technical
InChI	1S/C5H13ClSi/c1-5(6)7(2,3)4/h5H,1-4H3
InChI key	UWJVDEZZIPJQRF-UHFFFAOYSA-N
Quality Level	100
refractive index	n20/D 1.422
SMILES string	CC(Cl)[Si](C)(C)C

Other Notes:	Treating this chlorosilane with sec-BuLi gives 1-chloro-1-trimethylsilylethyl lithium which reacts with aldehydes and ketones to form methyl ketones via an intermediate α,β-epoxysilane.; Used in an efficient synthesis of R(+)-frontalin; The Grignard reagent is useful for many reactions
Packaging:	5 mL in glass bottle

Symbol	GHS02,GHS07
Signal word	Danger
Hazard statements	H225 - H315 - H319 - H335
Precautionary statements	P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	F
Risk Statements	11
Safety Statements	16-23-24/25
RIDADR	UN 1993BF 3 / PGII
WGK Germany	WGK 3
Flash Point(F)	68.0 °F
Flash Point(C)	20 °C

Purity	≥90% (GC)
bp	116 °C (lit.)
Density	0.864 g/mL at 20 °C (lit.)
Refractive Index	n20/D 1.422
UNSPSC	12352100

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