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n-Butyllithium solution

ALDRICH/230715 - 11.0 M in hexanes

Synonym: n-BuLi; Butyl lithium; Butyllithium solution; Lithium-1-butanide

CAS Number: 109-72-8
Empirical Formula (Hill Notation): C4H9Li
Molecular Weight: 64.06
MDL Number: MFCD00009414
Linear Formula: CH3(CH2)3Li
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-230715-4X25ML 25 mL
$117.00
4/EA
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45-230715-100ML 100 mL
$123.00
1/EA
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25 mL Sure/Sealâ„¢ Packaging

 

concentration 11.0 M in hexanes
density 0.761 g/mL at 25 °C
form liquid
InChI 1S/C4H9.Li/c1-3-4-2;/h1,3-4H2,2H3;
InChI key MZRVEZGGRBJDDB-UHFFFAOYSA-N
Quality Level 100 
SMILES string [Li]CCCC
storage temp. 2-8°C
Application: n-BuLi can be used as a reagent for lithium-halogen exchange reactions. Synthesis of various other useful reagents such as lithium diisopropylamide (LDA) and diphenylphosphine is prepared by in situ reaction with n-BuLi . In the polymerization of dienes, it can be employed as an initiator.
General description: n-Butyllithium (n-BuLi) is an organolithium reagent commonly used as a strong base to form corresponding lithium salts by the deprotonation of nitrogen, oxygen, phosphorus, and carbon acids. Heterocyclic compounds, such as furans, thiophenes, oxazoles, pyrroles, etc, can be lithiated α to the ring heteroatom using n?BuLi. These lithiated salts reacting in situ with alkyl halides to obtain useful organic compounds by the formation of the C-C bond.
Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging: 4×25, 100 mL in Sure/Seal™
Packaging: The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Symbol GHS02GHS05GHS07GHS08GHS09  GHS02,GHS05,GHS07,GHS08,GHS09
Signal word Danger
Hazard statements H225 - H250 - H260 - H304 - H314 - H336 - H361f - H373 - H411
Precautionary statements P210 - P231 + P232 - P280 - P301 + P310 + P331 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes F,C,N
Risk Statements 11-14/15-17-34-48/20-51/53-62-65-67
Safety Statements 26-36/37/39-43-45-61-62
RIDADR UN 3394 4.3(4.2) / PGI
WGK Germany WGK 2
Flash Point(F) -7.6 °F - closed cup
Flash Point(C) -22 °C - closed cup
Supplemental Hazard Statements EUH014
Density 0.761 g/mL at 25 °C
Storage Temp. 2-8°C
UNSPSC 12352103

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