Tributyltin hydride
ALDRICH/234788 - contains 0.05% BHT as stabilizer, 97%
Synonym: TBTH; Tri-n-butylstannane; Tri-n-butyltin hydride; Tributylstannane
CAS Number: 688-73-3
Empirical Formula (Hill Notation): C12H28Sn
Molecular Weight: 291.06
MDL Number: MFCD00009416
Linear Formula: [CH3(CH2)3]3SnH
Product Type: Chemical
assay | 97% |
bp | 80 °C/0.4 mmHg (lit.) |
contains | 0.05% BHT as stabilizer |
density | 1.082 g/mL at 25 °C (lit.) |
form | liquid |
InChI | 1S/3C4H9.Sn.H/c3*1-3-4-2; |
InChI key | DBGVGMSCBYYSLD-UHFFFAOYSA |
reaction suitability | reagent type: reductant |
refractive index | n |
SMILES string | [H][Sn](CCCC)(CCCC)CCCC |
storage temp. | 2-8°C |
Application: | A widely used radical reagent used in reductive cleavage, radical dehalogenation, and intramolecular radical cyclization. |
Application: | Radical promoted intramolecular cyclization leading to isoxazolo-benzaulene ring system. Vinyl tin fragment used in a synthesis of (+)-panepophenanthrin via biomimetic Diels-Alder dimerization. |
Packaging: | 10 g in glass bottle |
Packaging: | 50, 500 g in Sure/Seal™ |
Symbol | GHS02,GHS06,GHS08,GHS09 |
Signal word | Danger |
Hazard statements | H226 - H301 - H312 - H315 - H319 - H360FD - H372 - H410 |
Precautionary statements | P210 - P273 - P280 - P301 + P310 - P303 + P361 + P353 - P305 + P351 + P338 |
Hazard Codes | T,N |
Risk Statements | 10-21-25-36/38-48/23/25-50/53 |
Safety Statements | 26-36/37-45-61 |
RIDADR | UN1992 - class 3 - PG 3 - EHS - Flammable liquids, toxic, n.o.s. |
WGK Germany | WGK 3 |
Flash Point(F) | 104.0 °F - closed cup |
Flash Point(C) | 40 °C - closed cup |
Purity | 97% |
bp | 80 °C/0.4 mmHg (lit.) |
Density | 1.082 g/mL at 25 °C (lit.) |
Refractive Index | n |
Storage Temp. | 2-8°C |
UNSPSC | 12352103 |