Methyl dichlorophosphite
ALDRICH/235229 - technical grade
Synonym: Methyl phosphorodichloridite
CAS Number: 3279-26-3
Empirical Formula (Hill Notation): CH3Cl2OP
Molecular Weight: 132.91
EC Number: 221-915-3
MDL Number: MFCD00000524
Linear Formula: CH3OPCl2
Product Type: Chemical
bp | 93-95 °C (lit.) |
density | 1.376 g/mL at 20 °C (lit.) |
form | liquid |
grade | technical grade |
InChI | 1S/CH3Cl2OP/c1-4-5(2)3/h1 |
InChI key | HCSDJECSMANTCX-UHFFFAOYSA |
mp | −91 °C (lit.) |
Quality Level | 100 |
refractive index | n |
SMILES string | COP(Cl)Cl |
Application: | Methyl dichlorophosphite has been employed in the preparation of: • phosphonamidate- and phosphonate-linked phosphonopeptides • 2-(2-iodophenyl)ethyl methyl phosphite derivative of an alcohol • deoxyoligonucleotides on a polymer support • cis- and trans-2-oxo-2-propionyl-1,3,2- • phosphorodichloridothioates • oxazaphosphorinanes |
Packaging: | 10, 50 g in ampule |
Symbol | GHS02,GHS05,GHS07 |
Signal word | Danger |
Hazard statements | H226 - H314 - H335 |
Precautionary statements | P261 - P280 - P305 + P351 + P338 - P310 |
Hazard Codes | C |
Risk Statements | 10-14-34-37 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 2920 3(8) / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | 77.0 °F - closed cup |
Flash Point(C) | 25 °C - closed cup |
Supplemental Hazard Statements | EUH014 |
bp | 93-95 °C (lit.) |
mp | −91 °C (lit.) |
Density | 1.376 g/mL at 20 °C (lit.) |
Refractive Index | n |
UNSPSC | 12352100 |