Cerium(III) nitrate hexahydrate
ALDRICH/238538 - 99% trace metals basis
Synonym: Cerium trinitrate; Cerous nitrate hexahydrate; Nitric acid cerium salt
CAS Number: 10294-41-4
Empirical Formula (Hill Notation): CeN3O9 · 6H2O
Molecular Weight: 434.22
EC Number: 233-297-2
MDL Number: MFCD00149631
Linear Formula: Ce(NO3)3 · 6H2O
Product Type: Chemical
assay | 99% trace metals basis |
form | crystals and lumps |
impurities | 1-2% La |
InChI | 1S/Ce.3NO3.6H2O/c;3*2-1(3 |
InChI key | QQZMWMKOWKGPQY-UHFFFAOYSA |
Quality Level | 200 |
reaction suitability | reagent type: catalyst core: cerium |
SMILES string | [Ce+3].[H]O[H].[H]O[H].[H |
Application: | Cerium (III) nitrate hexahydrate is widely used as a source of cerium, especially in the synthesis of micro- or nano-structured ceria (cerium oxide). Because of its high solubility and low decomposition temperature, cerium (III) nitrate hexahydrate is an ideal reagent for hydrothermal reactions, sol-gel processing, and co-precipitation and calcination reactions. Ceria is one of the best studied materials-platforms for catalysis and solid oxide fuel cells. Consequently scientists have developed well-controlled synthetic protocols using cerium (III) nitrate hexahydrate for preparing ceria nanoparticles including nano cubes, nanotubes, and nanorods. The tailorable synthesis facilitates using ceria as a catalyst support, for example leveraging the porosity of the microstructure to impregnate metals and metal alloys, or for example synthesizing ceria-based materials like ceria-zirconia. |
General description: | Cerium (III) nitrate hexahydrate is the most common form of cerium nitrate. It is a white-to-yellow crystalline salt, and it is highly soluble in water, alcohol, and acetone, although solutions can appear slightly hazy. Like many trivalent metal nitrates, cerium (III) nitrate hexahydrate has a low-melting point of only 57 °C and thermally decomposes at low temperatures too, beginning at 190 °C and proceeding rapidly at 280 °C with complete decomposition at 390-400 °C. |
Packaging: | 100, 500 g in poly bottle |
Symbol | GHS03,GHS05,GHS09 |
Signal word | Danger |
Hazard statements | H272 - H318 - H410 |
Precautionary statements | P210 - P273 - P280 - P305 + P351 + P338 + P310 - P370 + P378 - P501 |
Hazard Codes | O,Xi,N |
Risk Statements | 8-41-50/53 |
Safety Statements | 17-26-39-60-61 |
RIDADR | UN1477 - class 5.1 - PG 3 - EHS - Nitrates, inorganic, n.o.s., H |
WGK Germany | WGK 2 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 99% trace metals basis |
UNSPSC | 12352302 |