2-(Trimethylsilyl)ethoxymethyl chloride
ALDRICH/238902 - technical grade
Synonym: (2-
CAS Number: 76513-69-4
Empirical Formula (Hill Notation): C6H15ClOSi
Molecular Weight: 166.72
EC Number: 278-483-4
MDL Number: MFCD00009919
Linear Formula: (CH3)3SiCH2CH2OCH2Cl
Product Type: Chemical
| bp | 170-172 °C (lit.) |
| 57-59 °C/8 mmHg (lit.) | |
| density | 0.942 g/mL at 25 °C (lit.) |
| form | liquid |
| functional group | chloro |
| ether | |
| grade | technical grade |
| InChI | 1S/C6H15ClOSi/c1-9(2,3)5- |
| InChI key | BPXKZEMBEZGUAH-UHFFFAOYSA |
| Quality Level | 100  |
| refractive index | n |
| SMILES string | C[Si](C)(C)CCOCCl |
| storage temp. | −20°C |
| Application: | Phenol protecting group in the synthesis of laterifluorones. |
| Application: | Used to prepare a SEM-ether which was, in turn, removed with BBr3 and cyclized to a benzo-oxapane. |
| Features and Benefits: | Convenient hydroxyl-protecting reagent. SEM-ethers are stable over a wide pH range, and can be selectively cleaved with fluoride ion under mild aprotic conditions. |
| General description: | Learn More at the Professor and Product Portal of Professor Bruce Lipshutz. |
| Packaging: | 1, 5, 25, 100 g in glass bottle |
| Symbol |   GHS02,GHS05 |
| Signal word | Danger |
| Hazard statements | H226 - H314 |
| Precautionary statements | P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310 |
| Hazard Codes | C |
| Risk Statements | 10-34 |
| Safety Statements | 26-28-36/37/39-45 |
| RIDADR | UN 2920 3(8) / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 114.8 °F - closed cup |
| Flash Point(C) | 46 °C - closed cup |
| bp | 170-172 °C (lit.); 57-59 °C/8 mmHg (lit.) |
| Density | 0.942 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| Storage Temp. | −20°C |
| UNSPSC | 12352101 |