Trimethyl phosphite
ALDRICH/240907 - ≥99%
Synonym: Methyl phosphite; P(OMe)3; Trimethoxyphosphine
CAS Number: 121-45-9
Empirical Formula (Hill Notation): C3H9O3P
Molecular Weight: 124.08
EC Number: 204-471-5
MDL Number: MFCD00008350
Linear Formula: (CH3O)3P
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 240907-100G.
| assay | ≥99% |
| bp | 111-112 °C (lit.) |
| density | 1.052 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C3H9O3P/c1-4-7(5-2)6-3 |
| InChI key | CYTQBVOFDCPGCX-UHFFFAOYSA |
| mp | −78 °C (lit.) |
| Quality Level | 200  |
| reaction suitability | reagent type: ligand reaction type: Heck Reaction |
| reagent type: ligand reaction type: Suzuki-Miyaura Coupling |
|
| refractive index | n |
| SMILES string | COP(OC)OC |
| vapor density | 4.3 (vs air) |
| vapor pressure | 17 mmHg ( 20 °C) |
| Application: | Trimethyl phosphite can be used as a ligand in the synthesis of allyliridium phosphite complexes by direct reaction with allyliridium 1,5-cyclooctadiene complex. |
| General description: | Trimethyl phosphite is an organophosphorus compound commonly used as a polymerization catalyst, coating additive, and as an intermediate in the synthesis of flame retardants. In addition, it is also used as an activating reagent in amide formation. |
| Packaging: | 25, 100 g in glass bottle |
| Symbol |   GHS02,GHS07 |
| Signal word | Warning |
| Hazard statements | H226 - H302 - H315 - H319 - H335 |
| Precautionary statements | P210 - P233 - P240 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 |
| Hazard Codes | Xn |
| Risk Statements | 10-22-37/38-41 |
| Safety Statements | 26-39 |
| RIDADR | UN 2329 3 / PGIII |
| WGK Germany | WGK 1 |
| Flash Point(F) | 82.4 °F - closed cup |
| Flash Point(C) | 28 °C - closed cup |
| Supplemental Hazard Statements | EUH014 |
| Purity | ≥99% |
| bp | 111-112 °C (lit.) |
| mp | −78 °C (lit.) |
| Density | 1.052 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352108 |