Tungsten(VI) chloride
ALDRICH/241911 - ≥99.9% trace metals basis
Synonym: Tungsten hexachloride
CAS Number: 13283-01-7
Empirical Formula (Hill Notation): Cl6W
Molecular Weight: 396.56
EC Number: 236-293-9
MDL Number: MFCD00011463
Linear Formula: WCl6
Product Type: Chemical
| assay | ≥99.9% trace metals basis |
| bp | 347 °C (lit.) |
| density | 3.52 g/mL at 25 °C (lit.) |
| form | powder |
| impurities | ≤1000.0 ppm Trace Metal Analysis |
| InChI | 1S/6ClH.W/h6*1H;/q;;;;;;+ |
| InChI key | KPGXUAIFQMJJFB-UHFFFAOYSA |
| mp | 275 °C (lit.) |
| Quality Level | 100 ![]() |
| reaction suitability | core: tungsten |
| reagent type: catalyst | |
| SMILES string | Cl[W](Cl)(Cl)(Cl)(Cl)Cl |
| vapor pressure | 43 mmHg ( 215 °C) |
| Application: | Tungsten(VI) chloride can be used:• As a starting material to synthesize tungsten nanoparticles and Mo-doped urchin-like W18O49 Nanostructure using the hydrothermal method. The Mo-W18O49 electrocatalyst exhibited excellent electrocatalytic activity toward Hydrogen Evolution Reaction (HER). By doping Mo species into defect-rich W18O49 ultrathin nanowires, it has also been demonstrated to be an excellent candidate for photocatalytic N2 fixation to ammonia. • To synthesize crystalline mesoporous WO3 with 11 nm pore size utilizing a high-molecular-weight amphiphilic block copolymer as the structure-directing agent. The materials performed admirably in terms of H2S gas sensing. • To fabricate Tungsten disulfide and WS2/reduced graphene oxide (WS2/rGO) nanosheets by hydrothermal synthesis. The WS2/rGO nanosheets showed exceptional electrocatalytic activity for the hydrogen evolution reaction. • To produce the WS2-nanoflowers@rGO and nitrogen-doped carbon spheres@WS2 composite as an anode material for enhanced electrode performance in lithium-ion batteries. • As a dopant to fabricate TiO2 compact layers for perovskite solar cells with enhanced performance. • As a catalyst to prepare self-healing epoxy composites with microcapsules. • As a catalyst for transamidation of tertiary alkyl amides. |
| General description: | Tungsten(VI) chloride is a highly reactive crystalline solid commonly used in the field of catalysis, perovskite solar cells, and light-emitting devices. It is a diamagnetic solid. However, it can be highly corrosive and have strong oxidizing effects. |
| Packaging: | 10, 100 g in glass bottle |
| Symbol | ![]() GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H314 - H335 - H412 |
| Precautionary statements | P260 - P271 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338 |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 3260 8 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥99.9% trace metals basis |
| bp | 347 °C (lit.) |
| mp | 275 °C (lit.) |
| Density | 3.52 g/mL at 25 °C (lit.) |
| UNSPSC | 12352302 |



