(Bromomethyl)cyclopropane
ALDRICH/242403 - 97%
Synonym: Cyclopropylmethyl bromide
CAS Number: 7051-34-5
Empirical Formula (Hill Notation): C4H7Br
Molecular Weight: 135.00
EC Number: 230-331-8
MDL Number: MFCD00001306
Linear Formula: C3H5CH2Br
Product Type: Chemical
assay | 97% |
bp | 105-107 °C (lit.) |
density | 1.392 g/mL at 25 °C (lit.) |
form | liquid |
InChI | 1S/C4H7Br/c5-3-4-1-2-4/h4 |
InChI key | AEILLAXRDHDKDY-UHFFFAOYSA |
Quality Level | 100 |
refractive index | n |
SMILES string | BrCC1CC1 |
Application: | (Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents. |
General description: | The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied. |
Packaging: | 1, 5 g in ampule |
Symbol | GHS02,GHS07 |
Signal word | Warning |
Hazard statements | H226 - H302 |
Precautionary statements | P210 - P233 - P240 - P241 - P242 - P301 + P312 |
Risk Statements | 10 |
Safety Statements | 23-24/25 |
RIDADR | UN 1993C 3 / PGIII |
WGK Germany | WGK 3 |
Flash Point(F) | 105.8 °F |
Flash Point(C) | 41 °C |
Purity | 97% |
bp | 105-107 °C (lit.) |
Density | 1.392 g/mL at 25 °C (lit.) |
Refractive Index | n |
UNSPSC | 12352100 |