Bis(1,5-cyclooctadiene)nickel(0)
ALDRICH/244988
Synonym: Bis(cyclooctadiene)
CAS Number: 1295-35-8
Empirical Formula (Hill Notation): C16H24Ni
Molecular Weight: 275.06
EC Number: 215-072-0
MDL Number: MFCD00058902
Linear Formula: C16H24Ni
Product Type: Chemical
InChI | 1S/2C8H12.Ni/c2*1-2-4-6-8 |
InChI key | JRTIUDXYIUKIIE-KZUMESAESA |
mp | 60 °C (dec.) (lit.) |
parameter | temperature sensitive |
reaction suitability | core: nickel |
reaction type: Cross Couplings | |
reagent type: catalyst | |
SMILES string | [Ni].C1CC=CCCC=C1.C2CC=CC |
storage temp. | −20°C |
Application: | Catalyst for the cycloaddition of 1,3-dienes. |
Application: | Reactant for: • Oxidative addition reactions Catalyst for: • Asymmetric α-arylation and heteroarylation of ketones with chloroarenes • Cross-coupling reactions • Regioselective and stereoselective carboxylation/cyclization of allenyl aldehydes under a carbon dioxide atmosphere • Methyl carboxylation of homopropargylic alcohols • Stereoselective borylative ketone-diene coupling • Cycloaddition of benzamides with internal alkynes |
Application: | Used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. The reaction with terminal acetylenes proceeds in high yield and high selectivity. A variety of functional groups are tolerated. |
Packaging: | 2 g in glass bottle |
Symbol | GHS02,GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H228 - H317 - H351 - H372 |
Precautionary statements | P201 - P202 - P210 - P280 - P302 + P352 - P308 + P313 |
Hazard Codes | F,Xn |
Risk Statements | 11-40 |
Safety Statements | 36/37 |
RIDADR | UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., H |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
mp | 60 °C (dec.) (lit.) |
Storage Temp. | −20°C |
UNSPSC | 12352202 |