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Triruthenium dodecacarbonyl

ALDRICH/245011 - 99%

Synonym: Ruthenium carbonyl; tri-Ruthenium dodecacarbonyl

CAS Number: 15243-33-1
Empirical Formula (Hill Notation): C12O12Ru3
Molecular Weight: 639.33
EC Number: 239-287-4
MDL Number: MFCD00011209
Linear Formula: Ru3(CO)12
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-245011-1G 1 g
 $129.00
1/EA		 Add To Favorites
45-245011-5G 5 g
 $460.00
1/EA		 Add To Favorites
45-245011-50G 50 g
 $3910.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 245011-50G.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 245011-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 245011-5G

 

assay 99%
form crystals
InChI 1S/12CO.3Ru/c12*1-2;;;
InChI key NQZFAUXPNWSLBI-UHFFFAOYSA-N
Quality Level 100 
reaction suitability core: ruthenium
  reaction type: C-H Activation
  reagent type: catalyst
SMILES string [Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
Application: Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.
Application: Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,ß-unsaturated ketones providing good yields of α-pyrones.
General description: Atomic number of base material: 44 Ruthenium
Other Notes: A Practical Procedure for Reduction of Primary, Secondary and Tertiary Amides to Amines 
Packaging: 1, 5, 50 g in glass bottle
Symbol GHS07  GHS07
Signal word Warning
Hazard statements H332
Precautionary statements P304 + P340 + P312
Hazard Codes Xn
Risk Statements 20
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 99%
UNSPSC 12161600

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