Triruthenium dodecacarbonyl
ALDRICH/245011 - 99%
Synonym: Ruthenium carbonyl; tri-Ruthenium dodecacarbonyl
CAS Number: 15243-33-1
Empirical Formula (Hill Notation): C12O12Ru3
Molecular Weight: 639.33
EC Number: 239-287-4
MDL Number: MFCD00011209
Linear Formula: Ru3(CO)12
Product Type: Chemical
assay | 99% |
form | crystals |
InChI | 1S/12CO.3Ru/c12*1-2;;; |
InChI key | NQZFAUXPNWSLBI-UHFFFAOYSA |
Quality Level | 100 |
reaction suitability | core: ruthenium |
reaction type: C-H Activation | |
reagent type: catalyst | |
SMILES string | [Ru].[Ru].[Ru].[C-]#[O+]. |
Application: | Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes. |
Application: | Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,ß-unsaturated ketones providing good yields of α-pyrones. |
General description: | Atomic number of base material: 44 Ruthenium |
Other Notes: | A Practical Procedure for Reduction of Primary, Secondary and Tertiary Amides to Amines |
Packaging: | 1, 5, 50 g in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H332 |
Precautionary statements | P304 + P340 + P312 |
Hazard Codes | Xn |
Risk Statements | 20 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 99% |
UNSPSC | 12161600 |