Bismuth(III) nitrate pentahydrate
ALDRICH/248592 - reagent grade, 98%
Synonym: Bismuth trinitrate pentahydrate
CAS Number: 10035-06-0
Empirical Formula (Hill Notation): BiN3O9 · 5H2O
Molecular Weight: 485.07
EC Number: 233-791-8
Linear Formula: Bi(NO3)3 · 5H2O
Product Type: Chemical
assay | 98% |
bp | 75-80 °C (lit.) |
form | crystals |
grade | reagent grade |
InChI | 1S/CH4.Bi.3NO3/c;;3*2-1(3 |
InChI key | DPLOIMSBRDLLRI-UHFFFAOYSA |
mp | 30 °C (lit.) |
Quality Level | 100 |
reaction suitability | core: bismuth |
reagent type: catalyst | |
SMILES string | O=[N+](O[Bi](O[N+]([O-])= |
Application: | An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. Convenient reagent for selective oxidation of sufides to sulfoxides. |
General description: | Bismuth(III) nitrate pentahydrate is the hydrated form of bismuth(III) nitrate. It is effectively used as a Lewis acid catalyst in organic synthesis for the conversion of thiocarbonyls to their carbonyl compounds; aromatic nitration; protection of carbonyl compounds; Michael reactions, and synthesis of coumarins. |
Packaging: | 100, 500 g in poly bottle |
Symbol | GHS03,GHS05 |
Signal word | Danger |
Hazard statements | H272 - H318 |
Precautionary statements | P210 - P220 - P280 - P305 + P351 + P338 - P370 + P378 - P501 |
Hazard Codes | O,Xi |
Risk Statements | 8-36/37/38 |
Safety Statements | 17-26-36 |
RIDADR | UN 1477 5.1 / PGII |
WGK Germany | WGK 2 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 98% |
bp | 75-80 °C (lit.) |
mp | 30 °C (lit.) |
UNSPSC | 12352300 |