Diphenylphosphine

ALDRICH/252964 - 98%

Synonym: HPPh₂; Ph₂PH

CAS Number: 829-85-6
Empirical Formula (Hill Notation): C₁₂H₁₁P
Molecular Weight: 186.19
EC Number: 212-591-4
MDL Number: MFCD00003040
Linear Formula: (C₆H₅)₂PH
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-252964-10G	10 g	$94.00 1/EA	Add To Favorites
45-252964-50G	50 g	$332.00 1/EA	Add To Favorites
45-252964-1KG	1 kg	$1580.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 252964-10G

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
bp	280 °C (lit.)
density	1.07 g/mL at 25 °C (lit.)
form	liquid
functional group	phosphine
InChI	1S/C12H11P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10,13H
InChI key	GPAYUJZHTULNBE-UHFFFAOYSA-N
Quality Level	200
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: ligand
refractive index	n20/D 1.625 (lit.)
SMILES string	C1(PC2=CC=CC=C2)=CC=CC=C1
vapor pressure	2 mmHg ( 110 °C)

Application:	Deprotonation of Ph2PH gives diphenylphosphide, used for synthesis of novel phosphine ligands, Wittig-Horner reagents, and phosphonium salts; source of phosphorus-centered radicals.
Packaging:	1 kg in Sure/Seal™
Packaging:	10 g in glass bottle
Packaging:	50 g in Sure/Seal™

Symbol	GHS02,GHS07
Signal word	Danger
Hazard statements	H250 - H315 - H319 - H335
Precautionary statements	P210 - P222 - P231 + P232 - P233 - P302 + P352 - P305 + P351 + P338
Hazard Codes	F,Xi
Risk Statements	17-36/37/38
Safety Statements	26-36
RIDADR	UN 2845 4.2
WGK Germany	WGK 3
Flash Point(F)	230.0 °F - closed cup
Flash Point(C)	110 °C - closed cup

Purity	98%
bp	280 °C (lit.)
Density	1.07 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.625 (lit.)
UNSPSC	12352002

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