Bismuth(III) chloride
ALDRICH/254142 - 99.99% trace metals basis
Synonym: Bismuth trichloride; Trichlorobismuth
CAS Number: 7787-60-2
Empirical Formula (Hill Notation): BiCl3
Molecular Weight: 315.34
EC Number: 232-123-2
MDL Number: MFCD00003461
Linear Formula: BiCl3
Product Type: Chemical
assay | 99.99% trace metals basis |
bp | 447 °C (lit.) |
form | solid |
impurities | ≤150.0 ppm Trace Metal Analysis |
InChI | 1S/Bi.3ClH/h;3*1H/q+3;;;/ |
InChI key | JHXKRIRFYBPWGE-UHFFFAOYSA |
mp | 230-232 °C (lit.) |
Quality Level | 100 |
reaction suitability | reagent type: catalyst core: bismuth |
SMILES string | Cl[Bi](Cl)Cl |
Application: | Bismuth(III) chloride can be used:• As a precursor to prepare polyaniline and bismuth(III) telluride nanohybrids with high thermoelectric performance. • As a starting material to synthesize visible light absorbing double perovskite semiconductors, such as Cs2AgBiBr6 and Cs2AgBiCl6, eco-friendly alternative to the lead halide perovskites. • To form a protective layer on anode materials. It can also be used as an efficient catalyst for green synthesis of:• Chalcones by Claisen–Schmidt reaction under solvent-free conditions. • One-pot three-component synthesis of Propargylamines. • Coumarins via ultrasound‐assisted Pechmann condensation of phenols with β‐ketoesters. |
General description: | Bismuth(III) chloride is a Lewis acid catalyst and a common source of Bi3+ ions used in various organic transformations and synthesis of bismuth nanomaterials. |
Packaging: | 25 g in poly bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 2 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 99.99% trace metals basis |
bp | 447 °C (lit.) |
mp | 230-232 °C (lit.) |
UNSPSC | 12352302 |