Trimethylsilyl cyclopentadiene, mixture of isomers

ALDRICH/257885

Synonym: NSC 176274

CAS Number: 3559-74-8
Empirical Formula (Hill Notation): C₈H₁₄Si
Molecular Weight: 138.28
MDL Number: MFCD00010666
Linear Formula: C₈H₁₄Si
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-257885-10G	10 g	$379.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

bp	138-140 °C (lit.)
density	0.833 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C8H14Si/c1-9(2,3)8-6-4-5-7-8/h4-8H,1-3H3
InChI key	VMFHCJPMKUTMMQ-UHFFFAOYSA-N
Quality Level	200
refractive index	n20/D 1.471 (lit.)
SMILES string	C[Si](C)(C)C1C=CC=C1
storage temp.	−20°C

Application:	Reactant involved in: • Diels-Alder reactions • Synthesis of ring-functionalized molybdenocene complexes • Allyl isomerization • Aromatization of C5 rings • Synthesis of N-hydroxyindoles via nucleophilic addition
General description:	Trimethylsilyl cyclopentadiene reacts with ruthenium trichloride in alcohol solvent to yield ruthenocene.
Packaging:	1, 10 g in glass bottle

Symbol	GHS02,GHS07
Signal word	Warning
Hazard statements	H226 - H315 - H319 - H335
Precautionary statements	P210 - P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	10-36/37/38
Safety Statements	16-26-36/37/39
RIDADR	UN 1993C 3 / PGIII
WGK Germany	WGK 3
Flash Point(F)	84.2 °F - closed cup
Flash Point(C)	29 °C - closed cup

bp	138-140 °C (lit.)
Density	0.833 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.471 (lit.)
Storage Temp.	−20°C
UNSPSC	12352100

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