Perrhenic acid solution
ALDRICH/261963 - 75-80 wt. % in H2O
Synonym: Hydrogen perrhenate; Hydrogen tetraoxorhenate
CAS Number: 13768-11-1
Empirical Formula (Hill Notation): HO4Re
Molecular Weight: 251.21
MDL Number: MFCD00011326
Linear Formula: HReO4
Product Type: Chemical
concentration | 75-80 wt. % in H2O |
density | 2.16 g/mL at 25 °C |
form | liquid |
InChI | 1S/H2O.3O.Re/h1H2;;;;/q;; |
InChI key | UGSFIVDHFJJCBJ-UHFFFAOYSA |
Quality Level | 100 |
reaction suitability | core: rhenium |
reagent type: catalyst | |
SMILES string | O[Re](=O)(=O)=O |
Application: | • Perrhenic acid solution (HReO4) can be used in dehydrations of oximes, amides, and urea. • HReO4 can also catalyze azeotropic dehydration of syn- or anti-aldoximes to yield corresponding nitriles. • In combination with tertiary arsines, it gives a versatile catalytic system for epoxidation of alkenes with hydrogen peroxide. |
Application: | It is also used to prepare highly conducting and superconducting synthetic metals. |
Packaging: | 5, 25 g in poly bottle |
Symbol | GHS05 |
Signal word | Danger |
Hazard statements | H314 |
Precautionary statements | P280 - P305 + P351 + P338 - P310 |
Hazard Codes | C |
Risk Statements | 34 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 3264 8 / PGII |
WGK Germany | WGK 1 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Density | 2.16 g/mL at 25 °C |
UNSPSC | 12352300 |