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Trimethylaluminum solution

ALDRICH/268569 - 2.0 M in hexanes

Synonym: Trimethylalane

CAS Number: 75-24-1
Empirical Formula (Hill Notation): C3H9Al
Molecular Weight: 72.09
MDL Number: MFCD00008252
Linear Formula: (CH3)3Al
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-268569-100ML 100 mL
 $137.00
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45-268569-800ML 800 mL
 $875.00
1/EA		 Add To Favorites
25 mL Sure/Seal™ Packaging

 

concentration 2.0 M in hexanes
density 0.683 g/mL at 25 °C
form liquid
InChI 1S/3CH3.Al/h3*1H3;
InChI key JLTRXTDYQLMHGR-UHFFFAOYSA-N
Quality Level 100 
SMILES string C[Al](C)C
Application: Used with 4-bromo-2,6-di-tert-butylphenol (cat. no. 394378) to prepare a wide range of carbonyl compounds via the selective rearrangement of epoxides.
General description: Trimethylaluminum is a Lewis acid having wide applications in organic synthesis. It is employed in organic reactions like cross-coupling reaction, methylenation, carboalumination, cyclopropanation, and rearrangement reactions. Tebbe Reagent (methylenation agent) can be prepared in situ by reacting trimethylaluminum with dichlorobis(cyclopentadienyl)titanium.
Packaging: 100, 800 mL in Sure/Seal™
Symbol GHS02GHS05GHS07GHS08GHS09  GHS02,GHS05,GHS07,GHS08,GHS09
Signal word Danger
Hazard statements H225 - H250 - H260 - H304 - H314 - H336 - H361f - H411
Precautionary statements P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes F,C,N
Risk Statements 11-14-17-34-48/20-51/53-62-65-67
Safety Statements 16-26-36/37/39-45-61-62
RIDADR UN3394 - class 4.2 - PG 1 - EHS - Organometallic substance, liqu
WGK Germany WGK 3
Flash Point(F) -0.4 °F - closed cup
Flash Point(C) -18 °C - closed cup
Supplemental Hazard Statements EUH014
Density 0.683 g/mL at 25 °C
UNSPSC 12352103

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