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Tributyl(1-ethoxyvinyl)tin

ALDRICH/275123 - 97%

Synonym: (1-Ethoxyvinyl)tri-n-butylstannane

CAS Number: 97674-02-7
Empirical Formula (Hill Notation): C16H34OSn
Molecular Weight: 361.15
MDL Number: MFCD00010240
Linear Formula: [CH3(CH2)3]3SnC(OC2H5)=CH2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-275123-1G 1 g
 $32.20
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45-275123-5G 5 g
 $153.00
1/EA		 Add To Favorites
45-275123-25G 25 g
 $710.00
1/EA		 Add To Favorites
45-275123-100G 100 g
 $1990.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 275123-100G.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 275123-1G.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 275123-5G.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 275123-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 275123-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 275123-5G

 

assay 97%
bp 85-86 °C/0.1 mmHg (lit.)
density 1.069 g/mL at 25 °C (lit.)
form liquid
InChI 1S/C4H7O.3C4H9.Sn/c1-3-5-4-2;3*1-3-4-2;/h1,4H2,2H3;3*1,3-4H2,2H3;
InChI key HGXJOXHYPGNVNK-UHFFFAOYSA-N
Quality Level 100 
refractive index n20/D 1.476 (lit.)
SMILES string CCCC[Sn](CCCC)(CCCC)C(=C)OCC
Application: Electrophilic methyl ketone equivalent used in a recent synthesis of a 13-oxophorbine (chlorophyll) from the corresponding 13-bromochlorin.
Application: Reagent employed in palladium-catalyzed coupling reactions with sulfoxides, α-haloethers, and chlorocyclobutenones. Also used to convert acid chlorides to α-oxygenated enones.
General description: This vinylstannane undergoes Stille coupling with a vinyl triflate, giving, after hydrolysis, an α,β−unsaturated ketone, thus acting as an acetyl anion equivalent.
Packaging: 1, 5, 25, 100 g in glass bottle
Purity 97%
bp 85-86 °C/0.1 mmHg (lit.)
Density 1.069 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.476 (lit.)
UNSPSC 12352103

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