Dichloro(1,5-cyclooctadiene)palladium(II)

ALDRICH/275891 - 99%

Synonym: PdCl₂(cod)

CAS Number: 12107-56-1
Empirical Formula (Hill Notation): C₈H₁₂Cl₂Pd
Molecular Weight: 285.51
EC Number: 235-161-8
MDL Number: MFCD00012412
Linear Formula: C₈H₁₂Cl₂Pd
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-275891-2G	2 g	$276.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	99%
InChI	1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
InChI key	RRHPTXZOMDSKRS-PHFPKPIQSA-L
mp	210 °C (dec.) (lit.)
Quality Level	100
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Cross Couplings
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst
SMILES string	Cl[Pd]Cl.C1CC=CCCC=C1

Application:	Catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes , Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate , and methoxycarbonylation of iodobenzene.
Application:	Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.
Packaging:	2 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	99%
mp	210 °C (dec.) (lit.)
UNSPSC	12352202

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