(1R)-(−)-Camphorquinone
ALDRICH/276286 - 99%
Synonym: (1R)-(−)-2,3-Bornanedione; 2,3-Bornanedione
CAS Number: 10334-26-6
Empirical Formula (Hill Notation): C10H14O2
Molecular Weight: 166.22
MDL Number: MFCD00082863
Linear Formula: C10H14O2
Product Type: Chemical
| assay | 99% |
| functional group | ketone |
| InChI | 1S/C10H14O2/c1-9(2)6-4-5- |
| InChI key | VNQXSTWCDUXYEZ-LDWIPMOCSA |
| mp | 200-203 °C (lit.) |
| optical activity | [α]20/D −101°, c = 2 in toluene |
| Quality Level | 100  |
| SMILES string | CC1(C)[C@@H]2CC[C@@]1(C)C |
| Application: | (1R)-(−)-Camphorquinone can be used as a chiral starting material for the preparation of: • α-Hydroxycamphors by selective reduction of keto groups using various vegetables. • Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies. • Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents. • Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement. |
| Packaging: | 5 g in glass bottle |
| Symbol |   GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H302 - H334 |
| Precautionary statements | P301 + P312 + P330 |
| Hazard Codes | Xn |
| Risk Statements | 22-43 |
| Safety Statements | 36/37 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 99% |
| mp | 200-203 °C (lit.) |
| UNSPSC | 12352115 |