Sodium biphenyl complex

ALDRICH/277134 - in 2-ethoxyethyl ether

Synonym: Biphenyl sodium complex solution; Sodium biphenyl complex

CAS Number: 5137-46-2
Empirical Formula (Hill Notation): C₁₂H₁₀ · Na
Molecular Weight: 177.20
MDL Number: MFCD00013182
Linear Formula: C₆H₅C₆H₅ · Na
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-277134-1PAK	15 mL	$246.00 20/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	in 2-ethoxyethyl ether
density	1.1 g/mL at 25 °C
form	liquid
functional group	phenyl
InChI	1S/C12H9.Na/c1-3-7-11(8-4-1)12-9-5-2-6-10-12;/h1,3-10H;
InChI key	UUNVZHGYJSUMDC-UHFFFAOYSA-N
packaging	pk of 20 × 15 mL
Quality Level	100
reaction suitability	reagent type: reductant
SMILES string	[Na]c1ccc(cc1)-c2ccccc2
vapor density	5.6 (vs air)

Application:	Sodium biphenyl can be used as a reagent:• for the decomposition of perfluorinated surfactants into inorganic fluoride ions, which facilitates their detection via fluorimetric flow injection analysis. • as a sodiation reagent in sodium-ion batteries (SIBs), in the chemical presodiation process for hard carbon (HC) anodes, enhancing their initial Coulombic efficiency.
General description:	Sodium biphenyl reagent is used to cleave the covalent fluorine bonds in organic compounds and biological samples. The liberated fluoride ions are determined spectrophotometrically or with the fluoride ion electrode.

Symbol	GHS02,GHS05,GHS09
Signal word	Danger
Hazard statements	H226 - H314 - H411
Precautionary statements	P210 - P233 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	C,N
Risk Statements	10-14-34-50/53
Safety Statements	26-36/37/39-45-61
RIDADR	UN2920 - class 8 - PG 2 - EHS - basic - Corrosive liquids, flamm
WGK Germany	WGK 3
Flash Point(F)	129.2 °F - closed cup
Flash Point(C)	54 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

Density	1.1 g/mL at 25 °C
UNSPSC	12352002

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