Diallyl carbonate

ALDRICH/281239 - 99%

Synonym: bis(prop-2-enyl) carbonate

CAS Number: 15022-08-9
Empirical Formula (Hill Notation): C₇H₁₀O₃
Molecular Weight: 142.15
EC Number: 239-106-9
MDL Number: MFCD00008645
Linear Formula: (H₂C=CHCH₂O)₂CO
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-281239-5G	5 g	$62.90 1/EA		Add To Favorites
45-281239-25G	25 g	$273.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	99%
bp	95-97 °C/60 mmHg (lit.)
density	0.991 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C7H10O3/c1-3-5-9-7(8)10-6-4-2/h3-4H,1-2,5-6H2
InChI key	JKJWYKGYGWOAHT-UHFFFAOYSA-N
Quality Level	100
refractive index	n20/D 1.428 (lit.)
SMILES string	C=CCOC(=O)OCC=C
storage temp.	2-8°C

Application:	Transesterification of diallyl carbonate with glycerol in the presence of a catalyst (Pd/PPh₃), generates glycerol carbonate.
General description:	Diallyl carbonate is an acrylating agent. Allyl carbonates are widely employed in Tsuji-Trost allylation, generating carbanion, boronate, phosphide, amide and alkoxide, nucleophiles in situ and improving reaction rates over allyl acetate. Allyl carbonates are also of considerable interest for the intramolecular decarboxylative assymetric couplings.
Packaging:	5, 25 g in glass bottle

Symbol	GHS02,GHS07
Signal word	Warning
Hazard statements	H226 - H315 - H319 - H335
Precautionary statements	P210 - P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36/37/39
RIDADR	UN 3272 3 / PGIII
WGK Germany	WGK 3
Flash Point(F)	138.2 °F - closed cup
Flash Point(C)	59 °C - closed cup

Purity	99%
bp	95-97 °C/60 mmHg (lit.)
Density	0.991 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.428 (lit.)
Storage Temp.	2-8°C
UNSPSC	12162002

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