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Magnesium bis(monoperoxyphthalate) hexahydrate

ALDRICH/283207 - 80%, technical grade

Synonym: MMPP

Empirical Formula (Hill Notation): C16H10MgO10 · 6H2O
Molecular Weight: 494.64
EC Number: 279-013-0
MDL Number: MFCD00149614
Linear Formula: (HO2CC6H4CO3)2Mg·6H2O
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-283207-100G 100 g
 $95.50
1/EA		 Add To Favorites
12 Principles of Green Chemistry: Principle 4—Designing Safer Chemicals
Chemical products should be designed to affect their desired function while minimizing their toxicity.

 

assay 80%
grade technical grade
greener alternative category Aligned ,  
greener alternative product characteristics Designing Safer Chemicals
Learn more about the Principles of Green Chemistry .
InChI 1S/2C8H6O5.Mg.6H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h2*1-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2
InChI key WWOYCMCZTZTIGU-UHFFFAOYSA-L
mp 93 °C (dec.) (lit.)
Quality Level 200 
reaction suitability reagent type: oxidant
SMILES string O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO
sustainability Greener Alternative Product
Application: A safer, greener oxidizing reagent that is a suitable replacement for peroxycarboxylic acids and is capable of effecting many types of oxidation reactions.

Oxidation Reactions Using Magnesium Monoperphthalate: A Comparison with m-Chloroperoxybenzoic Acid 
Application: Reagent for:
• Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
• Oxidation rections under mild conditions
• Epoxidation of unsaturated steroids
• Synthesis of ring-B oxygenated steroids as anticancer agents
General description: We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product MMPP is an alternative to widely used oxidant MCPBA as it is cheap, stable in the solid state, safer in handling and easier to use and thus aligns with the principle "Designing Safer Chemicals". For more information see the below articles.
Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones .
Magnesium Bis(monoperoxyphthalate) Hexahydrate (MMPP) .
Highly efficient epoxidation of unsaturated steroids using magnesium bis(monoperoxyphthalate) hexahydrate .
Packaging: 100 g in poly bottle
Purity 80%
mp 93 °C (dec.) (lit.)
UNSPSC 12352002

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