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Pentylmagnesium bromide solution

ALDRICH/290998 - 2.0 M in diethyl ether

Synonym: 1-Pentylmagnesium bromide; n-Pentylmagnesium bromide; Amylmagnesium bromide; Bromopentylmagnesium

CAS Number: 693-25-4
Empirical Formula (Hill Notation): C5H11BrMg
Molecular Weight: 175.35
MDL Number: MFCD00000045
Linear Formula: C5H11MgBr
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-290998-100ML 100 mL
 $132.00
1/EA		 Add To Favorites
45-290998-800ML 800 mL
 $411.00
1/EA		 Add To Favorites

 

concentration 2.0 M in diethyl ether
density 0.947 g/mL at 25 °C
InChI 1S/C5H11.BrH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1
InChI key ZXWGTPYWPZGZPT-UHFFFAOYSA-M
Quality Level 100 
reaction suitability reaction type: Grignard Reaction
SMILES string CCCCC[Mg]Br
Application: Pentylmagnesium bromide solution is a Grignard reagent that can be used in the preparation of:
• Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides.
• Hydroxypiperidinones via the addition-cyclization-deprotection process of aldimines.

It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.
Packaging: 100, 800 mL in Sure/Seal™
Density 0.947 g/mL at 25 °C
UNSPSC 12352001

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