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N-Phenyl-bis(trifluoromethanesulfonimide)

ALDRICH/295973 - 99%

Synonym: 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide; N,N-Bis(trifluoromethylsulfonyl)aniline; N-Phenyl-trifluoromethanesulfonimide; NSC 240874; Phenyl triflimide

CAS Number: 37595-74-7
Empirical Formula (Hill Notation): C8H5F6NO4S2
Molecular Weight: 357.25
MDL Number: MFCD00000404
Linear Formula: C6H5N(SO2CF3)2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-295973-5G 5 g
 $84.60
1/EA		 Add To Favorites
45-295973-25G 25 g
 $207.00
1/EA		 Add To Favorites

 

assay 99%
form solid
InChI 1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H
InChI key DIOHEXPTUTVCNX-UHFFFAOYSA-N
mp 100-102 °C (lit.)
SMILES string FC(F)(F)S(=O)(=O)N(c1ccccc1)S(=O)(=O)C(F)(F)F
Application: Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes

Reactant for:
Synthesis of amphoteric alpha-boryl aldehydes
Enantioselective synthesis of core ring skeleton of leucosceptroids A-D
Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate
Stereoselective sulfoxidation
Application: Mild triflating reagent.
Application: Used recently to convert a ketone to an enol triflate with KHMDS (324671) and thence an olefin with Pd(PPh3)4 (216666) and Bu3SnH (234788).
Packaging: 5, 25 g in glass bottle
Purity 99%
mp 100-102 °C (lit.)
UNSPSC 12352002

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