Synonym: (−)-10,2-Camphorsultam; (−)-exo-10,2-Bornanesultam; (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide; [3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide
CAS Number: 94594-90-8
Empirical Formula (Hill Notation): C10H17NO2S
Molecular Weight: 215.31
MDL Number: MFCD00066271
Linear Formula: C10H17NO2S
Product Type: Chemical
| assay |
98% |
| form |
solid |
| InChI |
1S/C10H17NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7-8,11H,3-6H2,1-2H3/t7-,8-,10-/m1/s1 |
| InChI key |
DPJYJNYYDJOJNO-NQMVMOMDSA-N |
| mp |
181-183 °C (lit.) |
| optical activity |
[α]19/D −32°, c = 5 in chloroform |
| SMILES string |
[H][C@@]12CC[C@]3(CS(=O)(=O)N[C@@H]3C1)C2(C)C |
| Application: |
(1S)-(−)-2,10-Camphorsultam may be used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It may be used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. |
| General description: |
(1S,2R,4R)-(−)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. |
| Packaging: |
5 g in glass bottle |
| Hazard Codes |
Xi |
| Risk Statements |
36/37/38 |
| Safety Statements |
26 |
| RIDADR |
NONH for all modes of transport |
| WGK Germany |
WGK 3 |
| Flash Point(F) |
Not applicable |
| Flash Point(C) |
Not applicable |
| Purity |
98% |
| mp |
181-183 °C (lit.) |
| UNSPSC |
12352005 |
