o-Tolylmagnesium bromide solution

ALDRICH/298980 - 2.0 M in diethyl ether

Synonym: 2-Methylphenylmagnesium bromide; 2-Tolylmagnesium bromide; o-Methylphenylmagnesium bromide; Bromo(2-methylphenyl)magnesium; Bromo-o-tolylmagnesium

CAS Number: 932-31-0
Empirical Formula (Hill Notation): C₇H₇BrMg
Molecular Weight: 195.34
MDL Number: MFCD00010350
Linear Formula: CH₃C₆H₄MgBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-298980-100ML	100 mL	$175.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	2.0 M in diethyl ether
density	1.013 g/mL at 25 °C
InChI	1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h2-5H,1H3;1H;/q;;+1/p-1
InChI key	DVXDIGKNJYSMFM-UHFFFAOYSA-M
reaction suitability	reaction type: Grignard Reaction
SMILES string	Cc1ccccc1[Mg]Br

Application:	o-Tolylmagnesium bromide solution can be used to prepare: • An iridium(I) mesityl complex named Ir(o-tolyl)(CO)(dppe). • 4-(2-Methylphenyl)-4-oxobutanoic acid, a key intermediate for the synthesis of M1 muscarinic selective agonist AC-42 derivatives.
Packaging:	100, 800 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07
Signal word	Danger
Hazard statements	H225 - H302 - H314 - H336
Precautionary statements	P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-14-19-22-34-67
Safety Statements	16-26-36/37/39-45
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 3
Flash Point(F)	-40.0 °F
Flash Point(C)	-40 °C
Supplemental Hazard Statements	EUH014 - EUH019

Density	1.013 g/mL at 25 °C
UNSPSC	12352103

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