Chlorobis(cyclooctene)rhodium(I),dimer

ALDRICH/302473 - 98%

Synonym: [Rh(coe)2Cl]2

CAS Number: 12279-09-3
Empirical Formula (Hill Notation): C₃₂H₅₆Cl₂Rh₂
Molecular Weight: 717.50
MDL Number: MFCD00013287
Linear Formula: C₃₂H₅₆Cl₂Rh₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-302473-250MG	250 mg	$131.00 1/EA		Add To Favorites
45-302473-1G	1 g	$360.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
form	powder
InChI	1S/4C8H14.2ClH.2Rh/c41-2-4-6-8-7-5-3-1;;;;/h41-2H,3-8H2;21H;;/q;;;;;;2+1/p-2/b4*2-1-;;;;
InChI key	GQPAPAIPOLEZHT-XFCUKONHSA-L
mp	190 °C (dec.) (lit.)
reaction suitability	core: rhodium
	reagent type: catalyst
SMILES string	Cl[Rh].Cl[Rh].C1CCCC=CCC1.C2CCCC=CCC2.C3CCCC=CCC3.C4CCCC=CCC4

Application:	Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst: • To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds. • In direct C-arylation of N-unprotected indoles and pyrroles. • In the carboxylation of arenes via C-H bond activation.
Packaging:	1 g in glass bottle
Packaging:	250 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 + H312 + H332 - H315 - H319 - H335
Precautionary statements	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	26-37/39
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	98%
mp	190 °C (dec.) (lit.)
UNSPSC	12161600

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