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Benzylmagnesium chloride solution

ALDRICH/302759 - 1.0 M in diethyl ether

Synonym: (Phenylmethyl)magnesium chloride; Benzylchloromagnesium; Chloro(phenylmethyl)magnesium

CAS Number: 6921-34-2
Empirical Formula (Hill Notation): C7H7ClMg
Molecular Weight: 150.89
MDL Number: MFCD00000469
Linear Formula: C6H5CH2MgCl
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-302759-100ML 100 mL
 $107.00
1/EA		 Add To Favorites
45-302759-800ML 800 mL
 $431.00
1/EA		 Add To Favorites

 

concentration 1.0 M in diethyl ether
density 0.794 g/mL at 25 °C
InChI 1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
InChI key NRAFPLGJPPJUNB-UHFFFAOYSA-M
reaction suitability reaction type: Grignard Reaction
SMILES string Cl[Mg]Cc1ccccc1
Application: Benzylmagnesium chloride solution (1.0 M in diethyl ether) is used as a reagent to provide the benzyl group required for the synthesis of the desired sulfonic acid-functionalized alkoxysilane. It is also used in the anionic polymerization of styrene to form styrenyl magnesium chloride, which is further used as an initiator in the synthesis of polyolefin-block-polystyrene block copolymers.
General description: Benzylmagnesium chloride is a versatile Grignard reagent frequently used in organic synthesis. It can be used as a reagent in the addition reaction with carbonyl compounds, nitriles, epoxides, and alkyl halides to synthesize various alcohols, amines, and ketones. Additionally, it is also used in reductions, cross-coupling, allylation and alkylation reactions.
Packaging: 100, 800 mL in Sure/Seal™
Density 0.794 g/mL at 25 °C
UNSPSC 12352103

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