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Perfluoro(methylcyclohexane)

ALDRICH/302937 - technical grade, 90%

Synonym: (Trifluoromethyl)undecafluorocyclohexane; Perfluoromethylcyclohexane

CAS Number: 355-02-2
Empirical Formula (Hill Notation): C7F14
Molecular Weight: 350.05
EC Number: 206-573-5
MDL Number: MFCD00001468
Linear Formula: C6F11CF3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-302937-25G 25 g
 $67.70
1/EA		 Add To Favorites
45-302937-100G 100 g
 $185.00
1/EA		 Add To Favorites

 

assay 90%
bp 76 °C (lit.)
density 1.787 g/mL at 25 °C (lit.)
form liquid
functional group fluoro
grade technical grade
InChI 1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12
InChI key QIROQPWSJUXOJC-UHFFFAOYSA-N
Quality Level 100 
refractive index n17/D 1.285 (lit.)
SMILES string FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F
Application: Perfluoro(methylcyclohexane) can be used as:
• A reactant to synthesize perfluoro-2-methylcyclohex-1-enolate by photochemical reaction with tetrabutylammonium iodide in water.
• A fluorous solvent to synthesize polynorbornene via ring-opening metathesis polymerization (ROMP) of norbornene using fluorous Grubbs′ second-generation catalyst.

It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.
Application: Perfluoro(methylcyclohexane) was employed as solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.
General description: Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated.
Packaging: 25, 100 g in ampule
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 90%
bp 76 °C (lit.)
Density 1.787 g/mL at 25 °C (lit.)
Refractive Index n17/D 1.285 (lit.)
UNSPSC 12352100

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