Titanium(IV) bromide
ALDRICH/307793 - 98%
Synonym: Titanium tetrabromide
CAS Number: 7789-68-6
Empirical Formula (Hill Notation): Br4Ti
Molecular Weight: 367.48
EC Number: 232-185-0
MDL Number: MFCD00011265
Linear Formula: TiBr4
Product Type: Chemical
| assay | 98% |
| bp | 230 °C (lit.) |
| density | 3.25 g/mL at 25 °C (lit.) |
| form | solid |
| InChI | 1S/4BrH.Ti/h4*1H;/q;;;;+4 |
| InChI key | UBZYKBZMAMTNKW-UHFFFAOYSA |
| mp | 38-40 °C (lit.) |
| Quality Level | 100 ![]() |
| reaction suitability | core: titanium |
| reagent type: catalyst | |
| SMILES string | Br[Ti](Br)(Br)Br |
| Application: | Titanium(IV) bromide (Titanium tetrabromide or TiBr4) can be employed as a Lewis acid catalyst in the synthesis of: • α-bromomethylene aldols by reacting with arylaldehydes and but-3-yn-2-one via Baylis-Hillman reaction. • Titanium(II) bromide which along with copper forms an efficient catalytic system for Pinacol reaction. • α-bromo-γ-hydroxyenamid |
| Features and Benefits: | Used for the formation of titanium silicide thin films on Si substrates. |
| Packaging: | 25, 100 g in glass bottle |
| Symbol | GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P280 - P305 + P351 + P338 - P310 |
| Hazard Codes | C |
| Risk Statements | 14-34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 3260 8 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Supplemental Hazard Statements | EUH014 |
| Purity | 98% |
| bp | 230 °C (lit.) |
| mp | 38-40 °C (lit.) |
| Density | 3.25 g/mL at 25 °C (lit.) |
| UNSPSC | 12161600 |


