Iron(III) perchlorate hydrate

ALDRICH/309281 - crystalline

Synonym: Perchloric acid iron(III) salt hydrate

CAS Number: 15201-61-3
Empirical Formula (Hill Notation): Cl₃FeO₁₂ · xH₂O
Molecular Weight: 354.20 (anhydrous basis)
EC Number: 236-908-0
MDL Number: MFCD00149705
Linear Formula: Fe(ClO₄)₃· xH₂O
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-309281-100G	100 g	$66.40 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 309281-100G

Properties
Descriptions
Safety Info.
Basic Data

color	yellow
form	crystalline
impurities	<0.10% chloride
InChI	1S/3ClHO4.Fe.H2O/c32-1(3,4)5;;/h3(H,2,3,4,5);;1H2/q;;;+3;/p-3
InChI key	PFPIMAZLJXJVAN-UHFFFAOYSA-K
reaction suitability	reagent type: oxidant
SMILES string	[Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

Application:	Catalyst for synthesis of: • Fullerene-fused lactones • α-Carbonyl furans via one-pot cyclization • Fullerodioxolanes via heterocyclization • Dialylated indoles via double alkylation • Aryl esters via oxidative esterification Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization
Application:	Iron(III) perchlorate hydrate is a useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units and in photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution. It can be used as a catalyst for synthesis of: • Fullerene-fused lactones • α-Carbonyl furans via one-pot cyclization • Fullerodioxolanes via heterocyclization • Fulleroxazolidines • Dialylated indoles via double alkylation • Aryl esters via oxidative esterification
Application:	Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.
Packaging:	100 g in glass bottle

Symbol	GHS03,GHS07
Signal word	Danger
Hazard statements	H272 - H315 - H319 - H335
Precautionary statements	P210 - P302 + P352 - P305 + P351 + P338
Hazard Codes	O,Xi
Risk Statements	8-36/37/38
Safety Statements	17-26-27
RIDADR	UN 1481 5.1 / PGII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

UNSPSC

12352000

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