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(Methoxymethyl)triphenylphosphonium chloride

ALDRICH/309567 - 97%

Synonym: Triphenyl(methoxymethyl)phosphonium chloride

CAS Number: 4009-98-7
Empirical Formula (Hill Notation): C20H20ClOP
Molecular Weight: 342.80
EC Number: 223-664-5
MDL Number: MFCD00011800
Linear Formula: (C6H5)3P(Cl)CH2OCH3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-309567-25G 25 g
 $65.10
1/EA		 Add To Favorites
45-309567-100G 100 g
 $135.00
1/EA		 Add To Favorites

 

assay 97%
form solid
InChI 1S/C20H20OP.ClH/c1-21-17-22(18-11-5-2-6-12-18,19-13-7-3-8-14-19)20-15-9-4-10-16-20;/h2-16H,17H2,1H3;1H/q+1;/p-1
InChI key SJFNDMHZXCUXSA-UHFFFAOYSA-M
mp 185-195 °C (dec.) (lit.)
reaction suitability reaction type: C-C Bond Formation
SMILES string [Cl-].COC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
Application: (Methoxymethyl)triphenylphosphonium chloride is a Wittig reagent that reacts with aldehydes and ketones to give substituted alkenes. This Wittig reaction finds application as the key step in the synthesis of:
• Antimalarial drug, (+)-artemisinin.
• Substituted quinolines.
• Akuammiline alkaloid picrinine.
• 7H-pyrrolo[2,3-d]pyrimidine derivatives for signal transducers and activators of transcription 6 (STAT6) inhibitors.
Packaging: 25, 100 g in glass bottle
Purity 97%
mp 185-195 °C (dec.) (lit.)
UNSPSC 12352107

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